Rory McIlroy and Tiger Woods will not face each other for the second Ryder Cup in a row.
American captain Davis Love has put Woods out last in Sunday's singles, while world number one McIlroy is out third against unbeaten Keegan Bradley as Europe try to claw back their four-point deficit.
Luke Donald leads things off for Jose Maria Olazabal's side and will play Masters champion Bubba Watson.
Saturday hero Ian Poulter, who like Bradley has won his first three games, follows against US Open champion Webb Simpson.
Woods faces Francesco Molinari just as he did at Celtic Manor two years ago. The Italian lost 4&3.